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Vol. 8. Issue 6.
Pages 6115-6124 (November - December 2019)
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Vol. 8. Issue 6.
Pages 6115-6124 (November - December 2019)
Original Article
DOI: 10.1016/j.jmrt.2019.10.006
Open Access
Green synthesis of iron oxide nanoparticles using pomegranate seeds extract and photocatalytic activity evaluation for the degradation of textile dye
Ismat Bibia, Nosheen Nazara, Sadia Atab, Misbah Sultanb, Abid Alic, Ansar Abbasa, Kashif Jilanid, Shagufta Kamale, Fazli Malik Sarimf, M. Iftikhar Khang, Fatima Jalalh,
Corresponding author

Corresponding authors.
, Munawar Iqbali,
Corresponding author

Corresponding authors.
a Department of Chemistry, The Islamia University of Bahawalpur, Bahawalpur, Pakistan
b Institute of Chemistry, University of the Punjab, Lahore, Pakistan
c Department of Allied Health Sciences, University of Lahore, Gujrat Campus, Pakistan
d Department of Biochemistry, University of Agriculture, Faisalabad, Pakistan
e Department of Applied Chemistry and Biochemistry, Government College University, Faisalabad, Pakistan
f Department of Botany, Qurtuba University of Science and Information Technology, Peshawar, Pakistan
g Department of Physics, University of Lahore, Lahore, Pakistan
h Department of Zoology, Government College University, Faisalabad, Pakistan
i Department of Chemistry, University of Lahore, Lahore, Pakistan
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Tables (2)
Table 1. Reports highlighting the biosynthesis of nanoparticles using plant extracts.
Table 2. Identification of phytochemicals in pomegranate (P. granatum) seed extract used for iron oxide NPs synthesis.
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Iron oxide nanoparticles (Fe2O3 NPs) were fabricated through green route using pomegranate (Punica granatum) seeds extract. The Fe2O3 NPs were characterized by UV–vis, XRD, EDX, SEM and AFM techniques. The adopted green rout furnished semi spherical Fe2O3 NPs, uniformly distributed and particle size in the range of 25–55 nm. The LCMS/MS was performed for the identification of biomolecule present in the extract of pomegranate seeds and p-hydroxy benzoic acid, gallic acid, methyl gallate, catechin, kaempferol-3-O-sophoroside, 3-deoxyflavonoids, magnolol, ferulic acid, vanillic acid and pinocembrin along with other minor constituents were detected in the extracts using for Fe2O3 NPs. The synthesized Fe2O3 NPs showed excellent photocatalytic activity against reactive blue under UV light irradiation and maximum degradation of 95.08% was achieved with 56 min of reaction time. In view of promising activity, the Fe2O3 NPs could be used photocatalyst for the degradation of dyes in wastewater and pomegranate seeds extract can be applied as eco-benign and cost effective approach for Fe2O3 NPs synthesis.

Punica granatum
Green synthesis
Iron oxide nanoparticles
Dye degradation
Full Text

Nano materials (1–100 nm) offers distinctive structural and physico-chemical properties as compared to bulk counterpart owing to the surface to volume ratio [1]. The most recent advancement in nanotechnology has led to the expansion in the synthesis of NPs by different chemical and physical methods. However, these methods have negative impact on the environment and living organisms since un-reacted chemicals are discharged in the environment. Therefore, there is need to fabricate the NPs using environmental benign techniques and NPs synthesized biogenically can be equally employed in electronics, biomedical field, material science and environmental remediation etc. [2–6]. In view of toxicity of nanoparticles, there is need to fabricate the NPs using bio-inspired agents. To date, the biosynthesis of NPs is regarded as environmental friendly approach since no toxic agent is involved in bio-inspired approaches [4–14]. Plants are nature’s “chemical factories” and vast repertoires of secondary metabolites [15–18] that can be utilized as redox mediator and stabilizer for the NPs. It is reported that the NPs synthesized using plant products/extracts are more stable and the rate of synthesis is easy as compared to conventional techniques since green approaches are eco-benign, cost effective, simple, easy to perform and no toxic agent is involved [19–23]. To date, metal and metal oxide NPs have been prepared successfully using green route and as-prepared NPs have been applied in different field (Table 1).

Table 1.

Reports highlighting the biosynthesis of nanoparticles using plant extracts.

S. no  Plant material  NPs  Properties and application  References 
C. maxima peel extract  Iron  NPs with diameters of 10–100 nm  [24] 
C. alata  Silver  Antibacterial activity against E. col, good tensile properties  [25] 
Lamiaceae plants (Mentha piperita, Melissa officinalis, and Salvia officinalisGold  Size of the produced Au NPs was dependent on the aqueous plant extract  [26] 
4Camellia SinensisNickelParticle size in 43.87–48.76 nm range  [12]
Promising photo-catalytic activity 
Peumus boldus  Silver  Size 18 nm, spherical, stable and pure  [27] 
Phlogacanthus thyrsiformis Hardow (Mabb) flower extract  Silver  Anti-urolithiatic activity  [28] 
T. involucrata, C. citronella, S. verbascifolium and T. ovata  Silver  Crystalline, monophasic Ag NPs, spherical, rod, flower and hexagonal shapes  [29] 
8Terminalia catappa leaf extractCopperExhibited good tensile strength and thermal stability.  [30]
Exhibited good antibacterial activity against E-col
H. fomes and S. apetala  Zinc oxide  Nano size, anti-inflammatory, antioxidant antibacterial, antidiabetic agents  [31] 
10  Rosa, Thymus, and Urtica dioica  Iron  Efficient in adsorption  [32] 
11  M. indica, M. Koenigii, A. indica, M. champacaIron  Efficient in adsorption  [33] 
12  R. officinalis and E. globulus  Gold  Sizes range was 60.7 and 8.66 nm, respectively  [26] 
13  A. scolopendrium  Silver  Antioxidant activity higher than extracts  [34] 
14  A. sativum, A. cepa and P. crispum  Zinc oxide  Size 14 and 70 nm, photo-active  [35] 
15  Diospyros sylvatica  Silver  Crystallite size 10 nm and antimicrobial agent  [36] 
16  Taxus baccata  Silver  Anticancer agent, non-toxic agent  [37] 
17  Green tea extracts  Iron  Photo-active  [38] 
18  Pelargonium endlicherianum  Silver  Antibacterial agent  [39] 
19  Nothapodytes nimmoniana  Silver  Size range 44-64 nm, antioxidant, anticancer, antimicrobial agent  [40] 
20  Pomegranate (P. granatumFe2O3  Semi-spherical, nano-range, 95.08% dye degradation  Present study 

In view of aforementioned facts, present study was focused on biogenic synthesis of for biogenic synthesis of Fe2O3 NPs using pomegranate seeds extract (PSE). The biomolecule in extracts was also identified using advanced techniques. The Fe2O3 NPs were prepared under mild conditions, characterized using UV–vis, XRD, SEM and AFM techniques and Fe2O3 NPs efficiency was studied by degrading the textile dye (reactive blue 4 dye, Fig. 1).

Fig. 1.

Structure of reactive blue 4 dye used for PCA evaluation.

2Material and methods2.1Chemical, reagents and sample collection

The PSE fruits were collected Bahawalpur, Pakistan (local market). The seeds were separated from fruits and used for extract preparation. Iron chloride (99.99%) was obtained from chemical supplier (Sigma-Aldrich). Ultrapure water (18.2 MΩ cm) was used for extraction and solution preparation purposes.

2.2Preparation of seed extracts of Punica granatum

The PSE were washed with ultrapure water and then, 20 g seeds were ground in electrical grinder and mixed with 250 mL of water and shaken for 2 h. The extract was filtered and filtrate was stored at 4 °C and used for the preparation of Fe2O3 NPs.

2.3Iron oxide NPs synthesis procedure

Both the PSE and iron chloride solution (1 M) were mixed in 1׃2 ratio and the mixture was heated at 70 °C for 15 min along with continuous stirring on magnetic stirrer till the pale yellow color changed to brownish black [41]. Then, it was centrifuged at 15,000 rpm for 10 min and precipitates were collected, which was washed with water and ethanol (3–4 times) and powder thus obtained was dried for 3 h in furnace at 60 °C and used for further analysis and PCA evaluation.


The UV–vis absorbance spectroscopy was performed using double beam spectrophotometer (CE Cecil 7200, UK). X-ray diffraction (XRD) analysis were recorded from 20° to 65° with a diffractometer (Bruker, German) using Cu Kα radiation with an accelerating voltage of 40 KV at scanning rate of 1°/min. The element analysis of Fe2O3 NPs was carried out using EDX analysis. The SEM was performed with a Hitachi SX-650 (Tokyo, Japan) at 20 KV of accelerating voltage. Moreover, the confirmation of the particle size and morphology was also carried out by atomic force microscopy (AFM).

2.5Photocatalytic activity

The PCA of fabricated NPs was evaluated by degrading reactive blue 4 dye. In a typical procedure, 15 mg of Fe2O3 NPs was added in 100 mL of 20 mg/L of reactive blue 4 dye (Fig. 1) and the suspension was placed in dark with slow stirring for 30 min to achieve the adsorption–desorption on the surface of catalysts. Then, mixture was irradiated to UV light (400 W high pressure mercury lamps). After specific time interval, sample was withdrawn (2 mL), absorbance was measured at 595 nm and percent degradation was measured as shown in Eq. (1). Where, C0 and Cf are the absorbance values before and after UV irradiation.

2.6HPLC analysis for degradation monitoring

RP-HPLC analysis was carried out to investigate the transformation of reactive blue 4 dye into by-products. For this purpose, control and treated samples were vortexed for 2 min and 15 uL of the sample was injected into ZORBAX SB C-column after filtration through 0.5 um syringe filter and eluted using 40% hexane at 0.5 mL/min (flow rate. The response was recorded at 550 and 600 nm and 200–900 nm was scanned in a diode array detector, whereas LCMS/MS was performed precisely as reported elsewhere [42].

3Results and discussion3.1Characterization

The Fe2O3 NPs was prepared via green route using P. granatum seeds (Fig. 2) extracts at room temperature. The absorption spectrum of Fe2O3 NPs is shown in Fig. 3 and the peak observed at 371.71 nm belong to Fe2O3 NPs, and is in line with already reported [43]. The morphology of Fe2O3 NPs was monitored by SEM analysis and the particle size was found in the range of 25–55 nm, the paricles were of variable shapes and in agglomerated form (Fig. 4). The agglomeration of agglomerated might be due to presence of biological compounds on the surface of particles. Due to H-bonding present in bioactive molecules, the particles appeared to be in the form of aggregates [12–14]. The EDX spectrum showed the presence of iron and oxygen (Fig. 5). The EDX analysis revealed the presence of 58.5% of iron and 17% oxygen along small amount of carbon, which was due to phenolic compounds in the extract of P. granatum. X-ray diffraction (XRD) is an important tool to study the crystal formation and to estimate the crystalline size of the fabricated NPs. The peaks observed in XRD analysis revealed the spinal structured magnetite and exhibiting peaks at 2 theta value of 30.60, 35.21, 42.13, 53.53, 57.6 and 63.01, which corresponds to diffraction planes of 220, 311, 400, 422, 511 and 440, respectively (Fig. 6). The formation of Fe2O3 NPs index with JCPDS card no: 82-1533 [44]. Analysis also revealed that the fabricated NPs were crystalline [45]. The average grain size was 48 nm, which was calculated using relation shown in Eq. (2). Where, λ is the wavelength of the X-rays (0.1541 Å), 0.90 is a constant value known as shape factor, ß is the FWHM and θ is the angle.

D = 0.9k/ßcosθ

Fig. 2.

Seeds and fruits of P. granatum used for the synthesis of Fe2O3 NPs.

Fig. 3.

UV–vis spectrum of Fe2O3 NPs synthesized using P. granatum seed extract.

Fig. 4.

SEM image of Fe2O3 NPs synthesized using P. granatum seed extract.

Fig. 5.

Energy dispersive X-ray (EDX) spectrum of Fe2O3 NPs synthesized using P. granatum seed extract.

Fig. 6.

X-ray diffraction (XRD) pattern of Fe2O3 NPs synthesized using P. granatum seed extract.


Moreover, AFM analysis was also performed to evaluate the nature of Fe2O3 NPs and response is shown in Fig. 7. The morphology of particles can be accessed from the grooves present in the dimensional views of NPs. From the three dimensional view, it is clearly observed that the size of the particle was variables and maximum distribution was in the range of 28.4–66.2 nm. This behavior of NPs was due to presence (coating) of different bioactive molecules [46–51], since bioactive molecules have different functional groups, which interact with each other by intermolecular forces, particle may hold together and particle size may vary. The existence of NPs in aggregates is an indication of strong intermolecular forces, especially H-bonding between hydroxyl groups and other moieties in the structure of phenolic compounds [4–6,12–14,50,52–54].

Fig. 7.

Atomic force microscopy of Fe2O3 NPs synthesized using P. granatum seed extract.

3.2Identification of bioactive constituents

The LC/MS/MS is ideal for the identification of bioactive constituents in seed extracts [55,56]. LC-ESI-MS/MS analysis is widely used for identification of bioactive molecules in plant extracts [57]. The molecules containing free carboxyl groups, yields [M−H] ion that corresponds to the carboxylate anion [58]. So far, LC-ESI-MS/MS analysis was used for the identification of phenolic compounds in extracts [59]. The constituents identified in the pomegranate (P. granatum) seeds extract are shown in Table 2, chromatograms are shown in Figs. 8 and 9 and the structures of representative compounds are shown in Fig. 10. The identified components were alkaloids, flavonoids and polyphenols in the seeds extract of P. granatum. The antioxidant activity of NPs was reported to be due the phenolic compounds that are used as capping and stabilizing agents. Phenolic compounds present in the extract contain hydroxyl and carboxylic groups which have very high tendency to bind heavy metals [53,60]. Metal ions in the salt solution interact with phenolic compound and due to p track conjugation (ester oxygen atom and ortho-phenolic hydroxyl group) and this esterification results in the loss of hydrogen from ortho-phenolic hydroxyl group [14] and a structure (semi-quinone) is produced due to H loss. H+ radical is formed due to the electron loosening form bioactive molecule (i.e., ellagic acid). Metal ions are to reduce to nano size during this process [12]. Also, bioactive molecule have excellent antioxidant property, which also furnished NPs by scavenging reactions along with the formation of H+ specie and resultantly, the ions in to solution are converted into stable atom [43].

Table 2.

Identification of phytochemicals in pomegranate (P. granatum) seed extract used for iron oxide NPs synthesis.

S. no  Molar Mass  m/z M (+/−)  MS/MS ions m/z (relative intensity)  Rt (min)  Compounds 
138  139  122, 121, 81, 69  0.75  p-Hydroxy benzoic acid 
170  169(−)  165, 150, 140, 100, 57  2.17  Gallic acid 
184  183(−)  168, 139, 124  0.67  Methyl gallate 
289  290  272, 260, 242, 124,93  6.92  Catechin 
302  301(−)  301, 257, 229, 185  8.67  Ellagic acid 
184  183(−)  168, 139, 124  0.67  Methyl gallate 
610  609(−)  607, 593, 565, 551, 489, 475,  2.72  Kaempferol-3-O-sophoroside 
226  225(−)  207, 189, 171, 159, 141, 129  1.12  3-Deoxyflavonoids 
198  199  190, 185, 175, 171, 161, 157, 143, 124, 103, 81, 63  0.89  Syringic acid 
10  265  266  251, 225, 171, 155  0.36  Magnolol 
11  270  269(−)  246, 110, 93, 91  1.95  Apigenin 
12  284  283(−)  242, 124  2.79  Retusin (isoflavone) 
13  454  455  437, 418, 381, 293, 275  2.13  Flavogallonic acid dilactone 
14  193  192(−)  175, 164, 120, 108  0.58  Ferulic acid 
15  391  390(−)  217, 191, 373  Citric acid derivative 
16  191  190(−)  111, 173  1.14  Citric acid 
17  255  254(−)  213, 211, 151  11.98  Pinocembrin 
18  168  169  151, 137, 111, 95, 82  8.77  Vanillic acid 
19  273  272  167  10.55  Phloretin 
20  433  432  301  7.93  Ellagic acid-pentoside 
21  447  446  300  8.21  Ellagic acid deoxyhexoside 
22  463  462  301  7.35  Ellagic acid-hexoside 
Fig. 8.

LC–MS analysis of P. granatum seed extract used for Fe2O3 NPs synthesis.

Fig. 9.

Representative chromatogram of methyl gallate of P. granatum seed extract analyzed by ESI-MS/MS.

Fig. 10.

Representative compounds extracted from P. granatum seed extract.

3.3Photocatalytic activity

The PCA of Fe2O3 NPs was evaluated by degrading the reactive blue 4 dye under UV light irradiation since photocatalysts are efficient for the degradation of recalcitrant and toxic agents [61–67]. Moreover, the photocatalytic treatment convert the pollutants completely in to harmless end products like carbon dioxide and water [68]. The dye degradation response of Fe2O3 NPs is shown in Fig. 11. It can be observed that the dye was degraded efficiently due to excellent activity of Fe2O3 NPs. The dye absorption peak was decreased rapidly as a function of UV irradiation time, which was due to breakdown of the chromophoric group in the dye and dye was degraded up to 95.08% in 56 min of reaction time. The dye degradation mechanism UV light irradiation in the presence of Fe2O3 NPs is elaborated in Fig. 12. When Fe2O3 NPs was irradiated, an electron (e) and hole (h+) pair is produced and electron is excited from valence band to the conduction band, leaving the h+ in the VB. This hole (h+) is actually responsible for the conversion of water into hydroxyl radical, which is responsible for oxidative degradation of dye. On the other hand, free electron combine with molecular oxygen and converted into superoxide radical. The superoxide radical is also converted in to hydroxyl radical. The hydroxyl radical is a strong oxidizing agent and degrades the organic species non-selectively in to harmless end products [69]. Reversed-phase chromatography (RP-HPLC) separates molecules on the basis of variation in their hydrophobicity. In order to investigate the degradation end products, the RP-HPLC analysis was performed before and after irradiation of dye and response thus obtained is shown in Fig. 13. The untreated dye shows a single peak at retention time of 1.86 min. A dye solution treated for 3 min showed peak of less intensity and after 56 min of irradiation, the peak at 1.86 min disappeared and peaks were appeared at 1.06, 2.02, 2.46, 3.61, 4.29, 5.37, 6.92, 7.36 and 8.44 min, which indicates that reactive blue 4 dye was complete degraded in to low molecular weight components and these findings are in line with previous studies [68,70] that after degradation the organic species are converted in to harmless end products [71–74]. Also, under the current scenario of environmental pollution [63,64,75–78], there is a need to adopt efficient approaches for the remediation of toxic pollutants and photocatalyic treatment using Fe2O3 NPs is proved to be highly efficient, which could possibly be used for the treatment of textile wastewater contains dyes.

Fig. 11.

UV–vis absorption spectra of reactive blue 4 dye (0–56 min of UV irradiation in the presence of Fe2O3).

Fig. 12.

Proposed dye degradation mechanism by Fe2O3 NPs under UV irradiation.

Fig. 13.

HPLC chromatograms of treated (using Fe2O3 NPs as catalyst under UV irradiation) and untreated reactive blue 4 dye.


The Fe2O3 NPs were successfully fabricated via green route using pomegranate (P. granatum) seeds extract, which were confirmed by UV–vis, XRD, EDX SEM and AFM techniques. The adopted green route furnished Fe2O3 NPs in nano-range size, semi-spherical shape and in agglomerated form. The P. granatum seeds extract analysis revaled a variety of bioactive componets that act as a capping and stabilizing agents. The main constituents were p-hydroxy benzoic acid, gallic acid, methyl gallate, catechin, kaempferol-3-O-sophoroside, 3-deoxyflavonoids, magnolol, ferulic acid, vanillic acid and pinocembrin. The Fe2O3 NPs showed promising photocatalytic activity for reactive blue 4 dye degradation under UV light irradiation and up to 95.08% dye degradation was achived with 56 min of UV irradiation. Results revealed that P. granatum seeds extract is potential biomolecules that can be employed for Fe2O3 NPs synthesis since it is one of green, cost effective and eco-benign methods and Fe2O3 NPs could be used for dye degradation in wastewater. Future studies can be focused on the bioactivity profiling (antioxidant and antimicrobial activities) of Fe2O3 NPs prepared via green route.

Conflict of interest

The authors declare no conflicts of interest.

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Green synthesis, characterization and antimicrobial activity of silver nanoparticles using methanolic root extracts of Diospyros sylvatica.
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Anticancer effects of silver nanoparticles encapsulated by Taxus baccata extracts.
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Iron nanoparticles synthesized using green tea extracts for the fenton-like degradation of concentrated dye mixtures at elevated temperatures.
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The Effect of Pelargonium endlicherianum Fenzl. root extracts on formation of nanoparticles and their antimicrobial activities.
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Biological activities of silver nanoparticles from Nothapodytes nimmoniana (Graham) Mabb. fruit extracts.
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Green synthesis of silver and copper nanoparticles using ascorbic acid and chitosan for antimicrobial applications.
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Extraction methods, LC–ESI-MS/MS analysis of phenolic compounds and antiradical properties of functional food enriched with elderberry flowers or fruits.
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Characterization and evaluation of antibacterial activities of chemically synthesized iron oxide nanoparticles.
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Preparation and adsorption properties of monodisperse chitosan-bound Fe3O4 magnetic nanoparticles for removal of Cu(II) ions.
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T. Mengistie, A. Alemu, A. Mekonnen.
Comparison of physicochemical properties of edible vegetable oils commercially available in Bahir Dar, Ethiopia.
Chem Int, 4 (2018), pp. 130-135
D. Yeshiwas, A. Mekonnen.
Comparative study of the antioxidant and antibacterial activities of two guava (Psidium guajava) fruit varieties cultivated in Andasa Horticulture Site, Ethiopia.
Chem Int, 4 (2018), pp. 154-162
M. Gebrekidan, M. Redi-Abshiro, B.S. Chandravanshi, E. Ele, A.M. Mohammed, H. Mamo.
Influence of altitudes of coffee plants on the alkaloids contents of green coffee beans.
Chem Int, 5 (2019), pp. 247-257
A.S. Rao.
Isolation, absolute configuration and bioactivities of megastigmanes or C13 isonorterpinoides.
Chem Int, 3 (2017), pp. 69-91
L. Abate, M. Yayinie.
Effect of solvent on antioxidant activity of crude extracts of Otostegia integrifolia leave.
Chem Int, 4 (2018), pp. 183-188
C. Friday, U. Akwada, O.U. Igwe.
Phytochemical screening and antimicrobial studies of afzelia africana and detarium microcarpum seeds.
Chem Int, 4 (2018), pp. 170-176
A. Abebe, M. Abebe, A. Mekonnen.
Assessment of antioxidant and antibacterial activities of crude extracts of Verbena officinalis linn root or atuch (Amharic).
Chem Int, 3 (2017), pp. 172-184
B. Adaramola, A. Onigbinde.
Influence of extraction technique on the mineral content and antioxidant capacity of edible oil extracted from ginger rhizome.
Chem Int, 3 (2017), pp. 1-7
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Chemical constituents, antimicrobial and antioxidant properties of the aerial parts of Coccinia barteri.
Chem Int, 3 (2017), pp. 428-441
M. Kallenbach, I.T. Baldwin, G. Bonaventure.
A rapid and sensitive method for the simultaneous analysis of aliphatic and polar molecules containing free carboxyl groups in plant extracts by LC–MS/MS.
Plant Method, 5 (2009), pp. 1-11
O. Igwe, U. Obiukwu.
GC/MS characterization of volatile components of hydrocolloids from Irvingia gabonensis and Mucuna sloanei seeds.
Chem Int, 3 (2017), pp. 410-415
D.W. Johnson.
Contemporary clinical usage of LC/MS: analysis of biologically important carboxylic acids.
Clin Biochem, 38 (2005), pp. 351-361
T. Nishikaze, M. Takayama.
Study of factors governing negative molecular ion yields of amino acid and peptide in FAB, MALDI and ESI mass spectrometry.
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G. Dinelli, A.S. Carretero, R.D. Silvestro, I. Marotti, S. Fu, S. Benedettelli, et al.
Determination of phenolic compounds in modern and old varieties of durum wheat using liquid chromatography coupled with time-of-flight mass spectrometry.
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Evaluation of phenolic contents, free radical scavenging activity and functional group analysis of the leaf extract of a medicinal plant in Niger Delta region.
Chem Int, 3 (2017), pp. 250-257
M. Iqbal, J. Nisar, M. Adil, M. Abbas, M. Riaz, M.A. Tahir, et al.
Mutagenicity and cytotoxicity evaluation of photo-catalytically treated petroleum refinery wastewater using an array of bioassays.
Chemosphere, 168 (2017), pp. 590-598
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Textile wastewater in Tlemcen (Western Algeria): impact, treatment by combined process.
Chem Int, 3 (2017), pp. 314-318
M. Iqbal, M. Abbas, J. Nisar, A. Nazir.
Bioassays based on higher plants as excellent dosimeters for ecotoxicity monitoring: a review.
Chem Int, 5 (2019), pp. 1-80
G.N. Iwuoha, A. Akinseye.
Toxicological symptoms and leachates quality in Elelenwo, Rivers State, Nigeria.
Chem Int, 5 (2019), pp. 198-205
M. Laissaoui, Y. Elbatal, I. Vioque, G. Manjon.
Adsorption of methylene blue on bituminous schists from Tarfaya-Boujdour.
Chem Int, 3 (2017), pp. 343-352
A.O. Majolagbe, A.A. Adeyi, O. Osibanjo.
Vulnerability assessment of groundwater pollution in the vicinity of an active dumpsite (Olusosun), Lagos, Nigeria.
Chem Int, 2 (2016), pp. 232-241
A.O. Majolagbe, A.A. Adeyi, O. Osibanjo, A.O. Adams, O.O. Ojuri.
Pollution vulnerability and health risk assessment of groundwater around an engineering Landfill in Lagos, Nigeria.
Chem Int, 3 (2017), pp. 58-68
M. Iqbal, I.A. Bhatti.
Gamma radiation/H2O2 treatment of a nonylphenol ethoxylates: degradation, cytotoxicity, and mutagenicity evaluation.
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K. Qureshi, M.Z. Ahmad, I.A. Bhatti, M. Zahid, J. Nisar, M. Iqbal.
Graphene oxide decorated ZnWO4 architecture synthesis, characterization and photocatalytic activity evaluation.
J Mol Liq, 285 (2019), pp. 778-789
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By-product identification and phytotoxicity of biodegraded direct yellow 4 dye.
Chemosphere, 169 (2017), pp. 474-484
M. Salavati-Niasari, S. Banitaba.
Alumina-supported Mn(II), Co(II), Ni(II) and Cu(II) bis(2-hydroxyanil) acetylacetone complexes as catalysts for the oxidation of cyclohexene with tert-butylhydroperoxide.
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M. Goudarzi, N. Mir, M. Mousavi-Kamazani, S. Bagheri, M. Salavati-Niasari.
Biosynthesis and characterization of silver nanoparticles prepared from two novel natural precursors by facile thermal decomposition methods.
Sci Rep, 6 (2016), pp. 32539
T. Gholami, M. Salavati-Niasari, M. Bazarganipour, E. Noori.
Synthesis and characterization of spherical silica nanoparticles by modified Stöber process assisted by organic ligand.
Superlattices Microstruct, 61 (2013), pp. 33-41
M. Salavati-Niasari, F. Davar, M.R. Loghman-Estarki.
Long chain polymer assisted synthesis of flower-like cadmium sulfide nanorods via hydrothermal process.
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A.M. Alkherraz, A.K. Ali, K.M. Elsherif.
Removal of Pb(II), Zn(II), Cu(II) and Cd(II) from aqueous solutions by adsorption onto olive branches activated carbon: equilibrium and thermodynamic studies.
Chem Int, 6 (2020), pp. 11-20
M. Sasmaz, E. Obek, A. Sasmaz.
The accumulation of La, Ce and Y by Lemna minor and Lemna gibba in the Keban gallery water, Elazig Turkey.
Water Environ J, 32 (2018), pp. 75-83
M. Palutoglu, B. Akgul, V. Suyarko, M. Yakovenko, N. Kryuchenko, A. Sasmaz.
Phytoremediation of cadmium by native plants grown on mining soil.
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Cytotoxicity reduction of wastewater treated by advanced oxidation process.
Chem Int, 1 (2015), pp. 53-59
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Journal of Materials Research and Technology

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